Witryna14 gru 2024 · We investigate the CO oxidation into CO 2 catalyzed by a biomimetic Ni(II)-iminothiolate complex in the presence of the sacrificial oxidizing agent methylviologen. We propose a catalytic mechanism supported by the density functional theory analysis of reaction intermediates that agrees with available experimental observations and … Witryna5 maj 2024 · DOI: 10.1002/QUA.25555 Corpus ID: 34854371; Mechanistic study of CO/CO2 conversion catalyzed by a biomimetic Ni(II)‐iminothiolate complex …
6-Iminohexane-3-thiol C6H13NS - PubChem
Witryna14 gru 2024 · We investigate the CO oxidation into CO 2 catalyzed by a biomimetic Ni(II)-iminothiolate complex in the presence of the sacrificial oxidizing agent … WitrynaDOI: 10.1246/CL.2009.1168 Corpus ID: 96333093; A Novel Tridentate-N,N,S Iminothiolate Ligand That Leads to the Formation of S-Bridged Dinickel(II) and … key switch box
10.1016/j.jorganchem.2010.11.028 DeepDyve
WitrynaInformed by the NiII−Iminothiolate Complex Alexander M. Chang, Benjamin Rudshteyn, Ingolf Warnke, and Victor S. Batista* Department of Chemistry and Energy Sciences Institute, Yale University, New Haven, Connecticut 06520, United States * S Supporting Information ABSTRACT: A computational inverse design method suitable to assist the Witryna(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electro-chemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds. C WitrynaTreatment of dicyandiamide, 2-aminoethanethiol hydrochloride, and NiCl2·6H2O in water gave an S-bridged dinickel(II) complex, [Ni2(L)2]Cl2 ([1]Cl2), which contains novel … keyswitch call point